I think there is some confusion over Aircon service.
First the mechanical bits - they are very close in design to your fridge, how often doe's that get serviced? Most likely never, because it is a sealed system.
Of course the risk of leaks developing in a vehicle are much higher, get a leak, loose the gas, no aircon. Simple!
Note cost of 'service' after a leak, the cheapest will - remove the remains of the gas and air left behind, and replace with a fresh charge of gas if it is possible to pump down to a vacume, but the leak is not fixed nor is the oil replaced.
The most expensive service should do all of the above + top up the oil + remove water + if they are very good replace the dryer in the system. (If the refrigerant can leak out then air and water can leak in both prevent the system working hence there is a dryer in the system)
The other Aircon Service.
Kill off the bacteria in the air ducts, and if your lucky, change the Pollen or Cabin Air Filter.
The air coming in from outside (through the pollen/cabin filter) to be chilled will be warm and therefore will be carrying water vapour, when it meets the evaporator (the remover of heat) of the air con the air cools, and cannot carry the water, the water collects, and runs off the evaporator some will splash the inside of the air duct, bacteria like to be wet, and some some of them don't smell too good, they also can form into a slime and block the evaporator air passages.
It these bacteria the aircon service sets out to destroy.
It is usual to use a strong detergent with antibacterial properties such that when it dries it leaves an antibacterial coating.
Or it can be achieved as Motman has described above.